Pathways for Deactivating an Excited State Without Emission

Shown here is an illustration of the energy level diagram for a molecule exhibiting pathways for the deactivation of an excited state: vr is vibrational relaxation; ic is internal conversion; ec is external conversion; and isc is an intersystem crossing. The lowest vibrational energy for each electronic state is indicated by the thicker line. The electronic ground state is shown in black and the three electronic excited states are shown in green. The absorption, fluorescence, and phosphorescence of photons also are shown.

Figure10.48

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