Tag Archives: standard addition

Standard Addition by Serial Spikes

One approach for preparing standard additions is to spike equal volumes of the sample with different volumes of a standard and diluting each to the same final volume. An alternative form of standard additions is illustrated here. In this case … Continue reading

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Matrix Effects

Sometimes the solution matrix in which the analyte resides affects the relationship between the signal and the analyte’s concentration, as shown below. We call this a matrix effect. When matrix effects are present, we introduce a determinate source of error … Continue reading

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Two Ways to Prepare a Standard Addition

The illustration below shows one method for making a standard addition. The volumetric flask on the left contains a portion of the sample, Vo, and the volumetric flask on the right contains an identical portion of the sample and a … Continue reading

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Standard Addition Calibration Curve

Shown at the top is a set of six standard additions for the determination of Mn2+. The flask on the left is a 25.00-mL sample diluted to 50.00 mL. The remaining flasks contain 25.00 mL of sample and, from left … Continue reading

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